They are the embodiment of strength a beaming light of ambition and resilience in a world built by and for men they have taken their rightful place leading with grace and power. ![]() They stand tall and proud, ruling in the wild, It's an image that to me represents history in the making and how phenomenal power and beauty can co exist. One of my favorite images captured of this phenomenal woman is below, just after she was sworn in as madam president you can see her bodyguards on either side of her who are also the only women. She has promoted policies aimed at achieving social, economic, and political justice for all Tanzanians, however, I belive her greatest accomplishment since becoming president is how she has shown and inspired all the women young and old of East Africa to continue to belive in themselves, that anything is possible, no matter what the world says. She had previously served as Tanzania's Vice President from 2015 until 2021.Ĭonsidered a reformer since taking the presidency Samia has pushed for development and reforms in Tanzania. She was sworn in on 19 March 2021, succeeding John Magufuli after his death. Samia is the first female president of the country. ![]() I believe this is exactly what Samia Suluhu Hassan ( Madame President) did, she broke through the cultural barriers, went against the norm, and did what no Tanzanian woman has ever done before. Women are judged for being too flirty, too serious, too driven, and too maternal- why shouldn’t we just give it all up and be what we want! "Jana Harris" There comes a time in every woman’s life when she rejects the character society expects her to be, whether that be the straight-laced Good Girl, the Not Like the Other girl, or any other patriarchy-approved role. PS, This is me, pulling at my heart strings.Woman standing at a podium with two flags on either side of her Here's to a good year of genuinely heart-felt solos! Hopefully one of these will spark a revolutionary idea and help you avoid having to choreograph to that slow cover of that pop song on the radio because you can't find anything better.you know the song I'm talking about. I've compiled 10 songs from my music library that will provide all the lyrical and musical emotion you need to inspire a great piece of choreography. If you've found yourself in a similar situation, this list is for you. ![]() Often, finding a song that both the dancer and choreographer agree on is extremely challenging. Contemporary and lyrical solos are very popular and it seems that around this time of year I spend a lot of time looking for songs with "all the feels" that will not only pull the audience in, but also pull at their heart strings. Dancers decide they want to do a solo, so they and their choreographer go searching for the perfect song. Okay, yeah, it's back-to-school time, but I'm thinking about something else.solo time. But really, no matter where you teach, these songs could inspire great choreography in any venue! These song could be used for many different ages and styles, Hopefully these will help some of my UDA teachers who need a last minute (or back-up) idea. It's been challenging and exciting I've found quite wide selection! While I am saving some of my best ideas for myself, I certainly can't use all of them, so I thought I'd share. I have spent the past month or two searching for songs that capture these first-time life moments. The recital theme is "That's a First! Dances Inspired by Life's Fabulous First Moments." I have to admit that when I first heard the theme I thought, "What.? What does that mean?" But, as I've grown to understand the idea, I've become very excited for this theme! There are so many possibilities and so many personal memories that can be commemorated. Utah Dance Artists, one of the fabulous dance studios that I teach at, is dedicating their Spring 2016 Recital to these moments. ![]() First steps, first day of school, first kiss, first home.
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The formula for determining the hybridization of any substance is: There is an image linked below for your convenience. Specifically, one electron in the 3p orbital and another electron in the 3d orbital established the bonds between sulphur and oxygen. And the remaining two pairs of orbitals make up sulfur’s lone pair.Īre you curious about the two 3p electrons that were not involved in hybridization? Sulfur requires two unpaired electrons from the Sp2 hybridised orbitals in order to create two sigma bonds with oxygen. Now, 3s2 and 3p3 combine to generate Sp2 hybridization, which consists of 3 analogous orbitals with 2 paired and 2 unpaired electrons. When an electron is in an excited condition, it jumps from 3px to 3d orbital. ![]() Similarly, the ground state electronic arrangement of SO2 is 1s2 2s2 2p6 3s2 3s4. I would recommend understanding the theory first, then proceeding to the formal.Ī brief tip: when one s orbital combines with two p orbitals, Sp2 hybridization results in three equal s orbitals. Now, hybridization of SO2 can be comprehended in two ways: the first is through theory, and the second is through formula application. Next, we must learn about the hybridization of SO2. Lastly, remember to check the formal charge of each atom! Oxygen has two lone pairs, while sulphur has one. This will eventually complete the atom’s octet. ![]() We must position these remaining electrons around the atoms in accordance with the specifications. Subtracting that from the total number of valence electrons, we are left with 10 electrons. Consequently, the amount of electrons utilised in double bonds = 8 The molecule contains 2 oxygen atoms, therefore = 6*2 = 12Īfter drawing the skeletal structure, it is evident that no atoms can complete their octet with single bonds. In SO2, the valence electron of sulphur equals six. Using the following methods, formal charge calculations can be performed: Step 6 – Finally, it is essential to ensure that all atoms have the lowest feasible formal charge. Step 5: If double or triple bonds are required to satisfy the octet rule for all atoms, they must be formed. Always start with the electronegative atoms and then proceed to the electropositive atoms. The third stage is to create a skeleton structure with only single bonds.Īfter forming single bonds, the fourth step involves completing the octet of the atoms with the leftover electrons. The central atom is the atom with the maximum number of bonding sites. The second step is to identify the core atom. A ‘+’ signifies electron loss, whereas a ‘-‘ signifies electron gain. While doing so, be mindful of the + and – symbols. Step 1 – The first and most crucial step is determining the total amount of valence electrons in the molecule. Now let’s examine the process of drawing lewis structure: This structure allows us to determine the type and amount of bonds that comprise the molecule. The distribution of electrons around the atoms of a chemical is its Lewis structure. Now we will discuss essential concepts such as Lewis structure, molecular geometry, the MO Diagram, and SO2 hybridization.īefore diving into the lewis structure of SO2, let’s briefly explore the significance of lewis structure and the methods required to draw it. ![]() The melting point and boiling point are, respectively, -72☌ and -10☌. In terms of its characteristics, the molar mass of SO2 is 64,066 g/mol. In Commonwealth English, sulphur dioxide is spelt as sulphur dioxide. Because at the end, you will have a thorough understanding of the fundamentals of SO2 before moving on to the reactions. However, before reading through them, please read the following article. In addition to its primary function, which is the generation of sulfuric acid, SO2 has various purposes in the chemical industry. Have you ever wondered what generates the scent of burning matchsticks? The correct response is SO2! ![]() ![]() With her film having been released in 1989, she was the first Princess in 30 years, the last one having been Aurora, who's film was released in 1959. Ariel is the first Disney Princess to have not been born human and is also the first Disney Princess confirmed to have children as she and Eric have a daughter, Melody, in the sequel. Jodi Benson provides both the speaking and singing voices of Ariel in all Disney animated appearances. ![]() Aurora has the purest pedigree of any Disney Princess, being the first and only child of a king ( King Stefan) and also presumably marries Prince Phillip, the firstborn son, and heir of a king ( King Hubert).Īriel is the protagonist of the films The Little Mermaid, The Little Mermaid II (although the title of the main female protagonist is shared with Melody) and The Little Mermaid III: Ariel's Beginning, as well as The Little Mermaid Television Series, based off of the Danish fairytale by Hans Christian Anderson. Disney based theirs off the French version, which was based on the Italian version.Īurora has the distinction of being both the Princess with the least amount of screen time and singing more of her lines than speaking them. It is Italian and involves her falling under a spell after getting a splinter, and the rest is too grim to put on here. The original story is much darker than the Disney version. Mary Costa provides the voice/singing voice for Aurora, giving her a British accent. Cinderella is the first Disney Princess who is married into royalty (she marries Prince Charming).Īurora is the titular protagonist of the film Sleeping Beauty, based on the classic fairy tale involving a beautiful princess, a sleeping enchantment, and a handsome prince. Ilene Woods provides the voice/singing voice for Cinderella (Original Disney version), Jennifer Hale provides the voice of Cinderella in the sequels, Tami Tappan provides Cinderella's singing voice in Cinderella III.Ĭinderella is the first Disney Princess to have siblings (albeit step-siblings) and is 19 years old. She is based on the European fairy tale of the same name, of which several variations exist. At 14, she is the youngest of the official Disney Princesses.Ĭinderella is the titular protagonist of her eponymous film and two sequels and is the second Disney Princess. ![]() Her true love is the Prince, who is able to wake her from her eternal sleep with love's first kiss. Adriana Caselotti provides the voice/singing voice for Snow White. Snow White, the titular protagonist of the 1937 Disney animated film Snow White and the Seven Dwarfs, is a character based on the German fairy tale "Schneewittchen." Snow White has the honor of being the first Princess in the first Disney animated feature, paving the way for all subsequent princesses. Regardless of any actual title(s) possessed, each official Disney Princess is properly addressed (within the franchise) with the title of "Princess" preceding their name. Disney Princesses: Jasmine, Rapunzel, Snow White, Mulan, Moana, Aurora, Cinderella, Pocahontas, Tiana, Belle, Ariel, Merida and RayaĮach of the following thirteen women has been certified as an "Official Disney Princess." These princesses fall into the requirements listed above. ![]() ![]() Players need to ramp up the Multiplier to x30 to achieve the highest scores possible. It is very surprising to see the score, the world record of highest score on subway surfers was 2,000,001,660. They can be increased permanently by completing a set of 3 Missions. Multipliers make it possible to increase the score you achieve playing Subway Surfers and they decrease the amount of time it will take. Multipliers are essential in getting high scores in Subway Surfers. Use the following ideas to increase your score playing your favourite video game. Players can achieve 1,000,000 points, or even as high as 5,000,000, just by successfully avoiding obstacles, using the right items and picking up upgrades along the way to help increase their score. Subway Surfers High Score TipsĪchieving a high score playing Subway Surfers takes speed, timing and the ability to dodge the Inspector and his guard dog. Having the ability to check the upgrade window is key to completing missions and beating Subway Surfers. Got 2 million before my summer starts Im gonna try and beat this Akash guy and go all the way to diamond before May. earned 2,000,001,660 points in Subway Surfers. ![]() You can view the rewards possible by finding and opening Mystery Boxes by looking at the Mystery Box upgrade window. Top Rated 1 Records Found Highest Score In 'Subway Surfers' (Mobile) Karim Mayur Karim M. You can receive 100,000 coins or something of even more useful and fun. Mystery Boxes contain prizes players can use to increase the fun and enjoyment of playing. This continues until the Daily Challenge streak ends. Completing more Daily Challenges rewards players with another Super Mystery box for each completed. Players completing Daily Challenges for five consecutive days will receive a Super Mystery Box. ![]() Virtually every write-up on Takashi Miike's melodrama has gone out of its way to address certain issues of content. There are a number of slow spots, and the film doesn't close with much punch (it more or less just stops), but the resourcefulness and creativity on display here is certainly worth a look. McAbee deserves much credit for not letting the obvious financial limitations constrain his imagination the low-tech effects are quite effective in their retro feel, as is the use of still images. ![]() That in and of itself doesn't sound too odd, but imagine the story told with musical production numbers on a shoestring budget, and you'll start to get the idea of how bizarre-and hence compulsively watchable-this film is. McAbee, who also wrote and had a hand in the music, stars as the space traveler of the title, who takes a young man (Gregory Russell Cook) from the all-male planet of Mars to female-inhabited Venus as a vengeful professor (Rocco Sisto) out for blood follows close behind. Traditional film categorizations don't apply to Cory McAbee's truly one-of-a-kind, no-budget, black-and-white feature to use the strange combo term of "sci-fi musical western" still doesn't scratch the strange surface. Cynics can scoff all they want, but why, when it's simply easier to just surrender to the magic? This is because the fanciful flair places the audience squarely in the quirky mind of the heroine, but most of all it fits in with the film's idealistic vision of Paris as a sunny romantic wonderland. As in his famous directorial collaborations with Marc Caro, Amélie isn't lacking in visual razzle-dazzle and overall technical wizardry, but the flashy touches are used in a way that doesn't obscure the film's emotional core. The plot description could have come straight from any romantic comedy, and hence it doesn't begin to touch on the level of wit and imagination that Jeunet brings to the story. Yet when it comes to her own happiness, Amélie Poulain is less attentive, and when her apparent soulmate-a porn shop worker named Nino (Mathieu Kassovitz)-wanders into her life by chance, she does whatever she can to avoid formally meeting him. Irresistible ingénue Audrey Tautou stars in the title role, a winsome waitress in Paris who sets out to make life better (or, if you deserve it, worse) for those around her after returning a lost box of childhood artifacts to its rightful owner. These people speak as if being a shameless crowdpleaser is a bad thing, but if it gets the job done so beautifully-as this film does-what exactly is the problem? Jean-Pierre Jeunet's global sensation is such a relentless charmer that naturally a small but growing section of moviegoers have been vocally rebelling against it. We are a participant in the Amazon Services LLC Associates Program, an affiliate advertising program designed to provide a means for us to earn fees by linking to and affiliated sites.Īmélie (Le Fabuleux Destin d'Amélie Poulain) (R) All movies are graded out of four stars ( ) ![]() In result, that is how, in March 2016, element 113 was called ununtrium or with the symbol Uut. The pertinent recommendations setting-up that systematic nomenclature was published in 1978 see PAC 1979, Vol. While an element can have been claimed, before the claim has been validated and before the element is formally named, the element has a temporary name and symbol. In Nov 2018, a provisional report ON THE DISCOVERY OF NEW ELEMENTS was released by IUPAC/IUPAP. Criteria and guidelines for establishing priority of discovery of potential new elements are presented. While reviewing the discovery profiles of the transfermium elements in the early 90s’, IUPAC and IUPAP set up to establish a series of criteria that must be satisfied for the discovery of an element to be recognized. Details about the latest release are provided above. Details below provide multiple references to IUPAC journal in Pure and Applied Chemistry ( PAC) and magazine Chemistry International ( CI).Īssessing if an element has been “discovered” is not a simple task. regularly reviewing standard atomic weights.determining which elements belong to Group 3.defining Group 1-18 and collective names. ![]() setting up precise rules for how to name a new element.coordinating the naming of a new element, involving the research laboratory and allowing for public comments.assessing claims resulting in the validation and assignation of an element discovery.defining the structure of a temporary name and symbol.establishing the criteria for a new element discovery.In particular, IUPAC is directly involved in the following: IUPAC involvement covers various aspects of the table and data that it unveils, and several reports and recommendations, some quite recent, attest of that input. – Access at a full resolution of this Table as PDF (made available by King’s Center for Visualization in Science).īy virtue of its work in relation with the chemical elements, IUPAC can dispense a periodic table that is up-to-date. – Review the latest IPTEI element-by-element review including a chart of all known stable and radioactive isotopes for each element and examples practical applications of isotopic measurements and technologies – Explore the interactive version at /isotopes-matter (or see release) – Read “Atomic Weights: No Longer Constants of Nature”, Chem Int 33(2), 10–15 (2011), IUPAC Periodic Table of the Elements and Isotopes (IPTEI) for the Educational Community Coplen, Peter Mahaffy, Ian Mills, Roberto Marquardt, and more. ![]() Leigh, Sigurd Hofmann, Eric Scerri, Juris Meija, Norman E. See PAC (AOP ) for full details or visit Commission II.1 ĭownload the PDF version (letter size or A4) or A3 (PDF) or see earlier versionsĬheck out SPECIAL Chem Int Jan 2019 - International Year of the Periodic Table (IYPT) - with contributions by Jan Reedijk, Natalia Tarasova, G.J. For elements that lack isotopes with a characteristic isotopic abundance in natural terrestrial samples, the mass number of the nuclide with the longest confirmed half-life is listed between square brackets. The latest release of the Periodic Table (dated ) includes the most recent abridged standard atomic weight values released by the IUPAC Commission on Isotopic Abundances and Atomic Weights ( CIAAW), compiled as part of the 2021 Table of Standard Atomic Weights 2021. ![]() ![]() Recordings of a real crackling fire can be pretty disappointing-you’ll probably just hear white noise and a few pops. This tactic would have been easier 10 years ago when phonebooks were more common, but slapping a slab of meat is another alternative-albeit a slimy one.ĭownload this stock audio track of a punch. Some Foley artists recommend hitting a phone book to simulate the sound of landing a punch. A Phone Book (Or Slab of Meat) = Punching Waving a sheet of aluminum will produce thunder-like sounds and altering your movements will add realistic variation to the effect.ĭownload this stock audio track of thunder. ![]() The aluminum-as-thunder effect is a little more well-known, but no less fun. Bonus: no hay fever.ĭownload this stock audio track of walking through tall grass. The result will sound just like a person walking through tall grass. Place some shredded newspaper in a plastic bag and gently hit or jostle the bag. Move the bamboo quickly past the microphone and the whooshing sound it creates will sound like an arrow flying by.ĭownload this stock audio track of an arrow whoosh. If you’re running low on arrows or you’ve misplaced your bow, a small stick of bamboo will do the job. Just make sure that your hand isn’t in the way.ĭownload this stock audio track of gunshots. A staple gun also offers the user a lot more control than a real gun. The sound of a heavy staple gun is remarkably similar to a real gunshot. Storyblocks is also a safe and cost-effective option.ĭownload this stock audio track of snapping celery. This trick will save you a trip to the hospital-and to the courtroom. You have successfully created a bone-breaking sound without getting sued. Take a bunch of celery, hold the stalks together, and snap them in half. We also think that “Bacon and Rain” would be a great name for a band.ĭownload this stock audio track of bacon frying. You can test your bacon-hearing skills by watching the video below, where we challenge you to identify which sounds are rain and which are actually bacon. Substituting the sound of frying bacon for rain is weird-but ultimately genius. We’ve heard that the technique can be kind of difficult so you might need to invest in some practice coconuts.ĭownload this stock audio track of a walking horse. Coconuts = A Walking HorseĪlways a crowd favorite, the sound of a horse walking really can be created by hitting coconuts together. You can find all of these sound effects with unlimited downloads in our royalty-free Storyblocks library. Access the best video tips, design hacks, and deals straight to your inbox.īelow we’ve curated our top 13 favorite Foley sound effects, complete with descriptions of how each effect is made with household objects. ![]() ![]() This post apparently refers to an earlier version of Recalbox, this procedure does not currently make sense, do not get confused. It is not because you were unable to make it work that it is broken, I use this emulator without any problems, and I did not have to make any configuration or modifications to work, it was enough to add the correct recommend that you use the latest official version of Recalbox (do not use ready-made images from the internet, or outdated versions), and use the correct BIOS files (remembering that these files are copyrighted, so requesting or distributing them is against the forum rules). Why include the emulator when it's broken? You are "cheating" the MD5 checker, but that is not enough to "cheat" the Emulator: If you have a problem with the BIOS, or you are using the wrong MD5, or you have the wrong name or extension (remembering that they are case sensitive, name and extension). Now warning message is not shown but any PSX game I load, it just kick me out (just as before). I keep my bios.xml file unchanged, I use the correct BIOS, and everything works: ![]() add the bios in the es_bios.xml file, in the "psx section", like this : Hello Guys aapke athersx2 emulator me bhi missing bios and fix bios aisa kuch problem aa raha hai to dont worry problem fix ho Jayega.If some games still cannot be lauched, like me you can : In case its any use I am on a Macbook air. I also noticed this happening in Ace Combat 2 where all dialog and other important pieces of text were missing. I first noticed this when playing Persona 3 Portable the text in the save menus is missing. check that in the bios menu that psx bios are all valid Greetings, Im having an issue with PSP and PSX games where text is missing.This is the correct md5 value for the bios file Nano /recalbox/share_init/system/.emulationstation/es_bios.xml connect to your recalbox using ssh/putty :Ĭreate a session with hostname open the bios config file :.Plink RECALBOX -l root -pw recalboxroot mount -o remount, rw / run this ms-dos commands, to make recalbox's config files writable :.add the missing bios to the \RECALBOX\share\bios\ folder : SCPH1001.BIN, SCPH7001.BIN, scph5502.bin, SCPH1002.BIN, SCPH7002.BIN, SCPH101.BIN).get all missing bios for psx : the list is available in the bios menu / section psx (you can use a pack like BIOS_Recalbox_4.1_18.02.09).It also tells that there might be a problem with the md5 checksum and I confirm it is related. I had this error message this morning when I tried my psx games, related to missing libretro/pcsx_rearmed bios. ![]() Not only will you have all of your student perks while at Purdue, but we’ll toss in all of our world-class amenities as well, bringing you the best of on- and off-campus living. Not only will it save you the effort of finding a roommate, but it will help you make friends along the way.Īnd finally, at Aspire at Discovery Park, we want each of our residents to have the best college experience imaginable. We also understand that having roommates is a financially beneficial situation, which is why we have a roommate matching program in place that will help you find roommates with similar interests and lifestyles. On top of the flexibility we’ll offer with floor plans, we also aim to put your mind at ease with individual leases, so you only have to be responsible for your own lease and not your roommates’. Whether they want to live alone, with roommates, or just with a close friend, we have the right fit. The four-story, three-building community is set to feature a variety of studio, two-, and four-bedroom floor plans, guaranteeing that our residents can find the set up they want. So mark your calendars, we open in Fall 2019 and we can’t wait to have you as a resident here.Īspire at Discovery Park is Purdue’s newest student housing community. We have crafted a renter experience unlike any other, and we’ve tailored it specifically for students of Purdue University. ![]() Here at Aspire at Discovery Park, we don’t want to make anything more stressful than it needs to be. Aspire at Discovery Park is Purdue's premier smart home community opening Fall 2019! It can be a hassle to get everything lined up to make your college experience memorable and worthwhile. ![]() To streamline the process, you will have to use the AQL calculator to get AQL sample size, limits, and all the numbers you need quickly. The inspection report is attached to the documents for your shipment. The inspector can conduct a pre-shipment inspection before production commences and issue a pre-shipment inspection report. If you operate in Asia, you will need pre-shipment inspection certificates. The maximum length of the ruler (fully visible when displayed on a sufficient screen) is 20 inches, or 50 centimeters (500 millimeters) for the metric scale option. ![]() How To Measure Ring Size With String, Paper & Ruler. ![]() It certifies that the products pass the quality level and accompanies the shipment until it is delivered to you. With our online ring sizer, youll quickly find out the right size. Our online actual size ruler allows you to take measurements in millimeters, centimeters and inches all at once, giving you the most accurate information. The quality limits and AQL sample size will guide your AQL inspection and help the inspector to decide whether to pass or fail the shipment.Īfter completing the AQL inspection, the inspection agency will issue a shipment inspection certificate. For large orders, the best practice is to select the sample randomly from different batches over several production runs. Settings Background image : Protractor color : Rotate : Protractor radius : Move protractor : Scan QR code and open it on your phone To provide an easy-to-use, online ruler for anyone who needs one, regardless of device. 2 The Online Ruler creates a virtual instrument in two different units of measurement. If the measurement is incorrect - specify your screen size in inches manually. The inspector selects the sample randomly from the shipment and inspects for defects based on the acceptable and rejectable number of defects from the AQL table. 1 Make sure the application correctly detected the size of your device’s screen. AQL inspection is a process of determining whether the percentage of defective units in shipment is acceptable before shipping to the customer. |
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